Plasma Co-Polymerization of HMDSO and Limonene with an Atmospheric Pressure Plasma Jet

Plasma co-polymers (co-p) were deposited with an atmospheric pressure plasma jet (APPJ) using a precursor mixture containing hexamethyldisiloxane (HMDSO) and limonene. A coating fragments from both precursors siloxane, carbonyl nitrogen functional groups was deposited. The flow rate of limonene found to be important parameter for co-polymerization tune the formation structure groups. FTIR XPS analysis indicates that increasing higher proportion carbon is bound silicon. This related stronger incorporation into siloxane network weaker fragmentation HMDSO. mechanism nitroxide carboxyl can mainly differentiated in-plasma post-plasma reactions, respectively.